| Kusaka | Have Hitsugaya defeat him, and successfully complete Bleach Tower, Level 21. |
| Kaname Tousen | Vanquish him in Bleach Tower, Level 12. |
| Retsu Unohana | Successfully complete 'Unohana's Cooperation' in Free Time mode. Alternately, defeat her in Bleach Tower, Level 7. |
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| Shunsui Kyoraku | Successfully complete 'Kyoraku's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 11. |
| S. G. Yamamato | Successfully complete 'Yamamato's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 4. |
| Shaolin Fong (Soi Fon) | Successfully complete 'Soi fon's Cooperation' in Free Time mode. Alternately, defeat her in Bleach Tower, Level 5. |
| Shuuhei Hisagi | Successfully complete 'Hisagi's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 12. |
| Sajin Komamura | Successfully complete 'Komamura's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 10. |
| Yoruichi Shihouin (Current) | Successfully complete 'Yoruichi's Cooperation' in Free Time mode. Alternately, defeat her in Bleach Tower, Level 5. |
| Gin Ichimaru | Vanquish him in five turns (before Izuru) in Bleach Tower, Level 6. |
| Byakuya Kuchiki | Successfully complete 'Byakuya's Cooperation' in Free Time mode. Alternately, defeat him in Bleach tower, Level 9. |
| Izuru Kira | Successfully complete 'Izuru's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 6. |
| Hanatarou Yamada | Successfully complete 'Hanatarou's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 7. |
| Hinamori Momo | Successfully complete 'Hinamori's Cooperation' in Free Time mode. Alternately, defeat her in Bleach Tower, Level 8. |
| Renji Abarai | Successfully complete 'Renji's Cooperation' in Free Time mode. Alternately, defeat him in Bleach Tower, Level 9. |
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| Yoruichi Shihouin (Former) | Vanquish her in Bleach Tower, in the level she is in with Kisuke Urahara. |
